Metal Dihydrogen and ϒ-Bond Complexes Structure Theory and Reactivity /

According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties b...

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Bibliographic Details
Main Author: Kubas, Gregory J. (Author)
Corporate Author: SpringerLink (Online service)
Format: Electronic
Language:English
Published: Boston, MA : Springer US, 2001.
Series:Modern Inorganic Chemistry
Subjects:
Online Access:View fulltext via EzAccess
Table of Contents:
  • Background and Discovery of Dihydrogen Coordination
  • Synthesis and General Properties of Dihydrogen Complexes
  • Bonding and Activation of Dihydrogen and ? Ligands: Theory versus Experiment
  • Structural and NMR Studies of Dihydrogen Complexes
  • Intramolecular Dynamics of Dihydrogen-hydride Ligand Systems: Hydrogen Rotation, Exchange, and Quantum-mechanical Effects
  • Thermodynamics, Kinetics, and Isotope Effects of the Binding and Cleavage of ? Ligands versus Classical Ligands
  • Vibrational Studies of Coordinated Dihydrogen
  • Reactions and Acidity of Dihydrogen Complexes
  • Activation of Hydrogen and Related Small Molecules by Metalloenzymes and Sulfur Ligand Systems
  • Coordination and Activation of Si-H, Ge-H, and Sn-H Bonds
  • C-H Bond Coordination and Activation
  • Coordination and Activation of B-H and Other X-H and X-Y Bonds.