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131015s2013 gw | s |||| 0|eng d |
| 020 |
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|a 9783319016740
|9 978-3-319-01674-0
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|a 10.1007/978-3-319-01674-0
|2 doi
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|a QD146-197
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|a PNK
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|a SCI013030
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|a 546
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|a Blusch, Lina K.
|e author.
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|a The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist
|c by Lina K. Blusch.
|h [electronic resource] /
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|a Cham :
|b Springer International Publishing :
|b Imprint: Springer,
|c 2013.
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| 300 |
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|a XVIII, 158 p. 142 illus., 48 illus. in color.
|b online resource.
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|a text
|b txt
|2 rdacontent
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|a computer
|b c
|2 rdamedia
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|a online resource
|b cr
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|a text file
|b PDF
|2 rda
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|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
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|a General Introduction -- Objective -- Route to the Siamese-Twin Porphyrin -- Siamese-Twin Porphyrin LH4 -- Nickel and Copper Complexes -- Redox Properties -- Summary and Outlook -- Experimental Section -- APENDIX: Crystallographic Details -- Details on DFT calculations.
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|a This thesis describes the first and�long-sought�successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch�not only�explains the challenging�synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu�complexes.�She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. This study explores the first steps�and opens up�a new chemistry of expanded porphyrins with the potential to biomimetic applications.
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| 650 |
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|a Chemistry.
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| 650 |
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|a Chemistry, inorganic.
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| 650 |
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|a Bioorganic chemistry.
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| 650 |
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|a Chemistry, Organic.
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| 650 |
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4 |
|a Chemistry.
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| 650 |
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|a Inorganic Chemistry.
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| 650 |
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|a Bioorganic Chemistry.
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| 650 |
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|a Organometallic Chemistry.
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| 710 |
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|a SpringerLink (Online service)
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|t Springer eBooks
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| 776 |
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|i Printed edition:
|z 9783319016733
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| 830 |
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|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
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| 856 |
4 |
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|u https://ezaccess.library.uitm.edu.my/login?url=http://dx.doi.org/10.1007/978-3-319-01674-0
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| 912 |
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|a ZDB-2-CMS
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| 950 |
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|a Chemistry and Materials Science (Springer-11644)
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