STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface Supramolecular Ordering, Electronic Properties and Reactivity /

The self-assembly of large organic molecules has become a vividly explored and interdisciplinary field in science. One major goal is the tailored fabrication of highly ordered, molecular networks, which are stabilized on a metal surface. Metalloporphyrins receive particular attention, because their...

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Bibliographic Details
Main Author: Buchner, Florian. (Author)
Corporate Author: SpringerLink (Online service)
Format: Electronic
Language:English
Published: Berlin, Heidelberg : Springer Berlin Heidelberg, 2010.
Series:Springer Theses
Subjects:
Online Access:https://ezaccess.library.uitm.edu.my/login?url=http://dx.doi.org/10.1007/978-3-642-14840-8
Table of Contents:
  • Introduction
  • Principle of the STM
  • Origin of the Tunneling Current
  • Scanning Tunneling Spectroscopy
  • Contrast Mechanism of Molecular Adsorbates
  • Temperature Programmed Desorption
  • Low Energy Electron Diffraction
  • UHV System
  • Scanning Tunneling Microscope
  • Control Electronics and Vibration Isolation
  • Ag(111)
  • Porphyrinoids
  • Preparation of thin Porphyrinoid Layers
  • Vapor-deposition of Cobalt and Iron
  • Self-Assembly and Individual Appearance of Tetraphenylporphyrins on
  • Ag(111)
  • Self-Assembly and Individual Appearance of Cobalt(II)-Tetrakisditertbutylphenylporphyrins
  • on Ag(111)
  • Coordination of Iron and Cobalt Atoms by Tetraphenylporphyrin Monolayers
  • on Ag(111) and Formation of Metal(II)-Tetraphenylporphyrin
  • Different Aspects of 2H-Tetrakisditertbutylphenylporphyrin on Ag(111)
  • Direct Metalation of a Phthalocyanine Monolayer on Ag(111) with coadsorbed
  • Iron Atoms
  • Multicomponent Adlayers of Tetraphenylporphyrins on Ag(111)
  • Modification of the Growth of Iron on Ag(111) by Predeposited Organic
  • Monolayers
  • Geometric and Electronic Aspects of CoTPP upon Dosage of NO
  • Self-Assembly and Voltage-dependent Appearance of Octaethylporphyrins
  • Summary and Outlook.